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Winter to summer CO2 dynamics within landfast sea ice in McMurdo Sound (Antarctica) were investigated using bulk ice pCO2 measurements, air-snow-ice CO2 fluxes, dissolved inorganic carbon (DIC), total alkalinity (TA), and ikaite saturation state. Our results suggest depth-dependent biotic and abiotic controls that led us to discriminate the ice column in three layers. At the surface, winter pCO2 supersaturation drove CO2 release to the atmosphere while spring-summer pCO2 undersaturation led to CO2 uptake most of the time. CO2 fluxes showed a diel pattern superimposed upon this seasonal pattern which was potentially assigned to either ice skin freeze-thaw cycles or diel changes in net community production. In the ice interior, the pCO2 decrease across the season was driven by physical processes, mainly independent of the autotrophic and heterotrophic phases. Bottom sea ice was characterized by a massive biomass build-up counterintuitively associated with transient heterotrophic activity and nitrate plus nitrite accumulation. This inconsistency is likely related to the formation of a biofilm. This biofilm hosts both autotrophic and heterotrophic activities at the bottom of the ice during spring and may promote calcium carbonate precipitation.

Mass loss from the Antarctic Ice Sheet to the ocean has increased in recent decades, largely because the thinning of its floating ice shelves has allowed the outflow of grounded ice to accelerate. Enhanced basal melting of the ice shelves is thought to be the ultimate driver of change, motivating a recent focus on the processes that control ocean heat transport onto and across the seabed of the Antarctic continental shelf towards the ice. However, the shoreward heat flux typically far exceeds that required to match observed melt rates, suggesting that other critical controls exist. Here we show that the depth-independent (barotropic) component of the heat flow towards an ice shelf is blocked by the marked step shape of the ice front, and that only the depth-varying (baroclinic) component, which is typically much smaller, can enter the sub-ice cavity. Our results arise from direct observations of the Getz Ice Shelf system and laboratory experiments on a rotating platform. A similar blocking of the barotropic component may occur in other areas with comparable ice–bathymetry configurations, which may explain why changes in the density structure of the water column have been found to be a better indicator of basal melt rate variability than the heat transported onto the continental shelf. Representing the step topography of the ice front accurately in models is thus important for simulating ocean heat fluxes and induced melt rates.

Dronning Maud Land (DML) is a key area for the better understanding of the geotectonic history and amalgamation processes of the southern part of Gondwana. Here, we present comprehensive new zircon U–Pb–Hf–O, whole-rock Sm–Nd isotopic and geochemical data for late Neoproterozoic-Cambrian igneous rocks along a profile from central to eastern DML, which provides new insights into the crustal evolution and tectonics of the region. In central DML, magmatism dominantly occurred at 530–485 Ma, with 650–600 Ma charnockite and anorthosite locally distributed at its eastern periphery. In contrast, eastern DML experienced long-term and continuous granitic magmatism from ca. 650 Ma to 500 Ma. In central DML, the 650–600 Ma samples are characterized by highly elevated δ18O (7.5–9.5‰) associated with slightly negative to positive εHf(t) values (−1 to +3), indicating significant addition of high-δ18O crustal components, such as sedimentary material at the margin of the Kalahari Craton. Evolved Hf isotopic signatures (εHf(t) = −15 to −6) and moderately elevated O isotopic data (δ18O = 6–8‰) of the Cambrian granitic rocks from central DML indicate a significant incorporation of the pre-existing, old continental crust. In eastern DML, the suprachondritic Hf–Nd isotope signatures and moderate δ18O values of the late Neoproterozoic granites (650–550 Ma) from the Sør Rondane Mountains support the view that they mainly originated from crust of the Tonian Oceanic Arc Super Terrane (TOAST). The post-540 Ma granites, however, have more evolved Hf and Nd isotopic compositions, suggesting an increasing involvement of older continental components during Cambrian magmatism. Nd isotopes of the Cambrian granitic rocks in DML display an increasingly more radiogenic composition towards the east with model ages ranging from late Archean to Mesoproterozoic times, which is in line with the isotopic trend of the Precambrian basement in this region. The late Neoproterozoic (>600 Ma) igneous rocks in central and eastern DML were emplaced in two independent subduction systems, at the periphery of the eastern Kalahari Craton and somewhere within the Mozambique Ocean respectively. The accretion and assembly of the TOAST to the eastern margin of the Kalahari Craton and their collision with surrounding continental blocks was followed by extensive post-collisional magmatism due to delamination tectonics and orogenic collapse in the Cambrian. The late Neoproterozoic–Cambrian igneous rocks in DML thus record an orogenic cycle from subduction-accretion, continental collision to post-collisional process during and after the assembly of Gondwana.

This study focusses on the Grenville-age Maud Belt in Dronning Maud Land (DML), East Antarctica, which was located at the margin of the Proto-Kalahari Craton during the assembly of Rodinia. We present new U–Pb zircon ages and Hf–O isotope analyses of mafic and granitic gneisses exposed in the Orvin-Wohlthat Mountains and Gjelsvikfjella, central DML (cDML). The geochronological data indicate continuous magmatic activity from 1160 to 1070 Ma which culminated at 1110–1090 Ma, followed by high-grade metamorphism between 1080 and 1030 Ma. The majority of zircons from the Orvin-Wohlthat Mountains exhibit radiogenic Hf isotopic compositions corresponding to suprachondritic εHf (t) values and Mesoproterozoic model ages, indicating crystallization from predominantly juvenile magmas. However, the involvement of ancient sedimentary material, which were most likely derived from the adjacent Proto-Kalahari Craton, is revealed by a few samples with negative to neutral εHf (t) and significantly elevated δ18O values (8–10‰). Samples from further west, in Gjelsvikfjella have more mantle-like zircon O isotopic compositions and late Paleoproterozoic Hf model ages, indicating the incorporation of ancient, previously mantle-derived continental crust. The rocks in cDML, thus define part of an extensive Mesoproterozoic magmatic arc with subduction under the Proto-Kalahari margin. This involved significant growth of new continental crust, possibly related to slab retreat, accompanied by subordinate recycling of older crustal components. The Maud Belt has previously been correlated with the 1250–1030 Ma Natal Belt in southern Africa, which lay to the west in the context of Gondwana, although this assertion has recently been questioned. Our study supports the latter view in demonstrating that the continental arc magmatism in the Maud Belt appears to be temporally and tectonically unconnected to the accretion of (slightly older) juvenile oceanic islands in the Natal Belt, which, in contrast to the Maud Belt, show subduction polarity away from the craton. We thus speculate that the Namaqua-Natal to Maud Belt contact (exposed in the Heimefront Shear Zone) may represent a changed tectonic environment from arc/continent-continent collision to slightly younger continental margin orogenesis at the westernmost termination of this part of the global Grenville Orogen. The Maud Belt marks the beginning of a major, long-lived accretionary Andean-type tectonic regime on the eastern margin of Proto-Kalahari in the Meso-Neoproterozoic during Rodinia assembly and break-up until the formation of Gondwana.