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Enhancement of ocean alkalinity using calcium compounds, e.g., lime has been proposed to mitigate further increase of atmospheric CO2 and ocean acidification due to anthropogenic CO2 emissions. Using a global model, we show that such alkalinization has the potential to preserve pH and the saturation state of carbonate minerals at close to today's values. Effects of alkalinization persist after termination: Atmospheric CO2 and pH do not return to unmitigated levels. Only scenarios in which large amounts of alkalinity (i.e., in a ratio of 2:1 with respect to emitted CO2) are added over large ocean areas can boost oceanic CO2 uptake sufficiently to avoid further ocean acidification on the global scale, thereby elevating some key biogeochemical parameters, e.g., pH significantly above preindustrial levels. Smaller-scale alkalinization could counteract ocean acidification on a subregional or even local scale, e.g., in upwelling systems. The decrease of atmospheric CO2 would then be a small side effect.

East Antarctica probably formed by amalgamation of a number of cratons along distinct Ediacaran mobile belts, including the ca. 600-500 Ma East African-Antarctic Orogen (EAAO) that dissects Dronning Maud Land (DML). New field-work during the international expeditions Geodynamic Evolution of East Antarctica (GEA) I + II in the austral summers 2010/11 and 2011/12, and first geochronological results from eastern DML reveal a complex tectonic architecture across the belt. In western DML, the EAAO reworks older Mesoproterozoic crust of the Maud Belt; the westernmost boundary of the mobile belt is characterized by a major dextral transpressional shear zone. In central DML, a major magnetic anomaly, the Forster anomaly, was interpreted as a cryptic suture of the EAAO (Riedel et al. 2012). The area where the Forster anomaly crosses the DML mountains is poorly investigated so far, but appears to coincide with a major strike slip shear zone in the southern Kurze Mts. and the occurrence of major Ediacaran granulite bodies. East of the Forster anomaly, the magnetic anomaly pattern changes significantly and typical Maud type crust is not present any longer. GEA II targeted a range of nunataks between Sør Rondane and central DML that had never been visited previously (from Blåklettane and Bergekongen in the E to Urna and Sørsteinen in the W). These nunataks are dominated by medium- to high-grade metasedimentary and metavolcanic rocks of possibly Neoproterozoic age, including abundant marble and graphite schists. Sør Rondane in eastern DML, is dominated by two distinct blocks separated by the dextral Main Shear Zone. The northwestern block is still part of the eastern EAAO, where new SHRIMP zircon data from metamorphic rims provide ages of ca. 560 Ma. The southeastern block is made up of a TTG terrane, which provides four new SHRIMP zircon dates between 990-980 Ma, interpreted as igneous crystallization ages (oceanic arc). The TTG terrane shows limited tectonic overprint and is likely the southeastern foreland of the EAAO. Close to the contact of the two blocks grey geisses and augen-gneisses gave zircon crystallization ages of ca. 750 Ma, ages which were previously unknown from the EAAO. The Forster anomaly therefore separates distinctly different parts of the EAAO: a) a reworked, mainly Grenville-age crust to the W (the overprinted margin of the Kalahari Craton) and b) a part of the orogen dominated by Neoproterozoic accretionary tectonics to the E. This difference is also reflected in the geochemistry of voluminous late-tectonics granitoids across the belt.

Central Dronning Maud Land (CDML) in East Antarctica is an important region for understanding Rodinia and Gondwana supercontinent cycles. Zircon U-Pb dating and Hf-O isotopic data revealed by extensive sampling across CDML provide constraints on the timing and source of main magmatism and new insights into the crustal composition and evolution. SIMS zircon U-Pb ages indicate multi-stage magmatic activities from Mesoproterozoic to Cambrian times at 1160-1130 Ma, 1115-1100 Ma, 1090-1070 Ma, 780-750 Ma, 645-600 Ma and 530-485 Ma, as well as Mesoproterozoic metamorphism at 1085-1050 Ma recorded by zircon rims. This region was subjected a large-scale and long-lasting high-grade metamorphism during 600-500 Ma. Most 1160-1080 Ma granitic rocks exhibit εHf (t) values ranging from +5 and +8 and δ18O slightly higher than mantle value (6-7 ‰), indicating a main derivation from juvenile crust. The involvement of Paleoproterozoic continental materials, which were most likely from adjacent Kalahari Craton, is attested by minor samples with negative to neutral εHf (t) and significantly elevated δ18O values (8-10 ‰). The late Neoproterozoic (750-600 Ma) rocks, including anorthosite, charnockite and granite, display an evolved Hf isotopic composition and high δ18O values (7.5-9 ‰), suggesting a significant addition of crust-derived materials into the source. The data imply that in CDML, late Mesoproterozoic (Grenville-age) magmatism during the assembly of Rodinia is dominated by the addition of new crust with subordinate reworking of ancient crust. Subsequent subduction process associated with the break-up of Rodinia and assembly of Gondwana largely witnessed recycling of previous continental components. Combined with whole-rock geochemistry, it is speculated that the accretionary process along the Maud margin of Kalahari Craton lasted from the Mesoproterozoic, across the late Tonian (750 Ma) until Ediacaran to suture west and east Gondwana blocks.

One-year long records of temperature, salinity, and currents show seasonally varying, energetic oscillations with a dominant period of approximately 35 h on the upper continental slope of the southern Weddell Sea. The data set is sampled by five moorings deployed on the slope of the Crary Fan, east of the main outflow site of the Filchner overflow plume. The characteristics of the observed oscillations are compared to idealized coastal trapped waves inferred from a numerical code. The variability at 35 h period is identified as mode 1 waves with wavelengths less than 200 km and group velocity opposing the phase speed, indicating energy propagation toward east. Filchner Depression and the nearby ridges on the slope are suggested as the generation site where the dynamics associated with the overflow plume can force the variability. Historical time series at the overflow site are revisited to identify the source of previously reported variability at 3 and 6 day time scales. Mode 2 waves at wavelengths of about 100 and 1000 km were found to bear resemblance to the 3 day and 6 day variability, respectively. The seasonal variation in the energy in the 35 h band shows small but significant correlation with the low frequency easterly winds. The presence of coastal trapped waves along the continental slope of the Weddell Sea can increase the heat exchange across the shelf break and affect the dense water production rates.

We have examined changes in climate which result from the sudden termination of geoengineering after 50 years of offsetting a 1% per annum increase in CO2 concentrations by a reduction of solar radiation, as simulated by 11 different climate models in experiment G2 of the Geoengineering Model Intercomparison Project. The models agree on a rapid increase in global-mean temperature following termination accompanied by increases in global-mean precipitation rate and decreases in sea-ice cover. There is no agreement on the impact of geoengineering termination on the rate of change of global-mean plant net primary productivity. There is a considerable degree of consensus for the geographical distribution of temperature change following termination, with faster warming at high latitudes and over land. There is also considerable agreement regarding the distribution of reductions in Arctic sea-ice, but less so for the Antarctic. There is much less agreement regarding the patterns of change in precipitation and net primary productivity, with a greater degree of consensus at higher latitudes.

Rapid climate change recorded in the western Antarctic Peninsula confronts species with less predictable conditions in the marine and terrestrial environments. We analysed the breeding chronology and nesting site selection of gentoo penguins (Pygoscelis papua) at King George Island (Isla 25 de Mayo), Antarctica, during four seasons in which differences in snow presence and persistence on the ground were observed. We recorded an overall delay as well as seasonal asynchrony at the beginning of reproduction for those years with higher snow deposition. A redistribution of breeding groups was also observed. Nevertheless, the population breeding success and chicks’ weight at fledging remained relatively constant, despite the delay in breeding chronology, the increased duration of foraging trips during the guard stage and the decreased weight of stomach contents during the crèche stage. We suggest that the plasticity of their trophic biology, along with the flexibility of their breeding phenology and relocation of breeding groups, may be complementary reasons why gentoo penguin populations in the region have remained stable in spite of the changing conditions currently registered. Keywords: Antarctica; breeding delay; breeding phenology; snow; Pygoscelis papua; Euphausia superba.

A first long-term monitoring of selected persistent organic pollutants (POPs) in Antarctic air has been conducted at the Norwegian research station Troll (Dronning Maud Land). As target contaminants 32 PCB congeners, α- and γ-hexachlorocyclohexane (HCH), trans- and cis-chlordane, trans- and cis-nonachlor, p,p'- and o,p-DDT, DDD, DDE as well as hexachlorobenzene (HCB) were selected. The monitoring program with weekly samples taken during the period 2007–2010 was coordinated with the parallel program at the Norwegian Arctic monitoring site (Zeppelin mountain, Ny-Ålesund, Svalbard) in terms of priority compounds, sampling schedule as well as analytical methods. The POP concentration levels found in Antarctica were considerably lower than Arctic atmospheric background concentrations. Similar to observations for Arctic samples, HCB is the predominant POP compound, with levels of around 22 pg m−3 throughout the entire monitoring period. In general, the following concentration distribution was found for the Troll samples analyzed: HCB > Sum HCH > Sum PCB > Sum DDT > Sum chlordanes. Atmospheric long-range transport was identified as a major contamination source for POPs in Antarctic environments. Several long-range transport events with elevated levels of pesticides and/or compounds with industrial sources were identified based on retroplume calculations with a Lagrangian particle dispersion model (FLEXPART).

In addition to the chemical analyses providing total nutrient content, standardized water trophic status bioassays are useful in the determination of available nutrients for primary producers. The aim of the study was to determine the standardized values of algal growth potential (AGP) and algal primary productivity rate (APPR) of maritime Antarctic stream water using modified AGP/APPR protocols. The standardized values of AGP and the APPR of oligotrophic and mesotrophic water samples from snow-melt streams were measured, and possible nutrient limitation and heavy metal inhibition were evaluated at 5°C and 25°C using polar and temperate strains of Stichococcus bacillaris, respectively. The water samples were enriched for the nutrient limitation tests with 1000 mμ l-1 NO3- -N, 50 μg l-1 PO43- -P, and a mixture of 1000 μg l-1 NO3- -N + 50 μg l-1 PO43- -P, and for the heavy metal inhibition tests with 1000 mg l-1 Na2-ethylenediaminetetraacetic acid (EDTA). The AGP of oligotrophic samples was significantly lower than that of the mesotrophic ones at both temperatures. In addition, AGP was significantly higher at 5°C than at 25°C. Oligotrophic samples were identified as being nitrogen limited, while no nutrient limitation was observed in the mesotrophic samples. No statistically significant heavy metal inhibition was observed at either temperature. The positive correlation of AGP and water nutrient content indicates that the method used accurately and comprehensively monitors the changes in biological availability of mineral nutrients and can provide a standardized reference point for similar exploration of freshwater ecosystems across both polar regions. Keywords: Maritime Antarctic; microalgae; nutrient limitations; snow-melt stream water.

Enhanced snowfall on the East Antarctic ice sheet is projected to significantly mitigate 21st century global sea level rise. In recent years (2009 and 2011), regionally extreme snowfall anomalies in Dronning Maud Land, in the Atlantic sector of East Antarctica, have been observed. It has been unclear, however, whether these anomalies can be ascribed to natural decadal variability, or whether they could signal the beginning of a long-term increase of snowfall. Here we use output of a regional atmospheric climate model, evaluated with available firn core records and gravimetry observations, and show that such episodes had not been seen previously in the satellite climate data era (1979). Comparisons with historical data that originate from firn cores, one with records extending back to the 18th century, confirm that accumulation anomalies of this scale have not occurred in the past ~60 years, although comparable anomalies are found further back in time. We examined several regional climate model projections, describing various warming scenarios into the 21st century. Anomalies with magnitudes similar to the recently observed ones were not present in the model output for the current climate, but were found increasingly probable toward the end of the 21st century.

Monitoring ice-sheet snowmelt is fundamental to understanding global climate change. A simple and automated snowmelt detection process is critical to the establishment of an ice-sheet snowmelt monitoring system. However, different ice-sheet snowmelt detection methods are based on a variety of thresholding schemes using different melt signals for dry and wet snow; these complicate the regular operation of an ice-sheet snowmelt monitoring. We propose an automated melt signal detection method developed using melt signals derived from the cross-gradient polarization ratio snowmelt detection method over Greenland and the wavelet transformation-based snowmelt detection method over Antarctica. Initial results indicate that the proposed method not only increases computational efficiency, practicability and operability but is also more accurate. Keywords: Ice sheet; snowmelt detection; radiometer; cross-gradient polarization ratio; wavelet transformation; generalized Gaussian model.

Maitri Station (70.76°S; 11.73°E) is located in Schirmacher Oasis, a coastal nunatak in north-central Dronning Maud Land covering an area of 35 km2. Here, we report results from the first magnetotelluric experiments and delineate the deep electrical conductivity structure under Schirmacher Oasis using the data acquired during the 24th Indian Antarctic Scientific Expedition. The magnetotelluric method has the advantage of shallow to deeper level coverage as the data acquisition covers a wide frequency band of 10-3103 Hz, permitting different penetration depths depending on the frequency and conductivity of the layer under investigation. The modelling results indicate the presence of a highly resistive (8000-10 000 ohm m) upper crust, which shows a lateral variation in thickness from 20 km (below site 6) in the east to 10 km (between sites 1 and 2) in the west. It is underlain by a less resistive (500-600 ohm m) lower crust. The highly resistive upper crustal structure supports the existing notion that western Dronning Maud Land is a stable, cratonic platform. Results of free-air gravity, seismic, geomagnetic and surface wave dispersion investigations in East Antarctica also indicate a cratonic-type crust. The results of our study allow us to identify a westward thinning of the upper crust with a marked boundary between sites 1 and 2. We also find evidence for the continuity of the Mozambique mobile belt in East Antarctica on the western side of Schirmacher Oasis. Keywords: Magnetotellurics; Schirmacher Oasis crustal structure; East Antarctica; Mozambique Belt; electrical conductivity.

We report ground-based measurements of the polar middle atmosphere made using a 230–250 GHz passive microwave radiometer deployed at Troll station (72°01′S 02°32′E, L shell of L = 4.8), Antarctica. Our observations show enhanced mesospheric nitric oxide (NO) volume mixing ratio (VMR) during a series of small recurrent geomagnetic storms in the 2008 austral winter, reaching 1.2 ppmv on day 200 (18 July). The Lomb normalized periodogram of the NO VMR time series averaged over 65-80 km for days 130 to 220 of 2008 (9 May to 7 August) shows a peak exceeding the 95% confidence limit at 25.8 days, close to the synodic rotation period for low-latitude solar coronal holes. The highest correlations between the radiometer NO VMR data and trapped and quasi-trapped electron count rates for L = 3.5-5.5 from the Polar Orbiting Environment Satellites 90° telescope are for the >30 keV (90e1) channel (rmax = 0.56, lag time of 5.1 days) and >100 keV (90e2) channel (rmax = 0.57, lag time of 4.4 days). Maximum correlation between NO VMR and the >700 keV (90P6) channel data is lower but lag times are close to zero. Superposed epoch analyses for the eight most significant geomagnetic storm periods and three Carrington rotations (2070-2072) within the 90 day observation period indicate that significant NO abundance observed at 65-80 km in the Antarctic mesosphere may be produced directly by >200 keV electron precipitation or originate from a source at higher altitudes, e.g., production by >30 keV electrons followed by downward transport.

In this study, we present evidence that Antarctic and Arctic sea ice act as sink for atmospheric CO2 during periods of snowmelt and surface flooding. The CO2 flux measured directly at the flooded sea ice surface (Fflood) constituted a net CO2 sink of −1.1 ± 0.9 mmol C m−2 d−1 (mean ± 1 SD), which was an order of magnitude higher than the flux measured at the snow-air surface (Fsnow) and bare ice surface (Fice). The Fsnow/Fflood ratio decreased with increasing water equivalent of snow and superimposed-ice, suggesting that the properties of snow and superimposed-ice formation affect the magnitude of the CO2 flux. The Fsnow/Fflood ratio ranged from 0.1 to 0.5, illustrating that 50–90% of the potential flux at the flooded surface was reduced due to the presence of snow/superimposed-ice. Hence, snow cover properties and superimposed-ice play an important role in the CO2 fluxes across the sea ice-snow-atmosphere interface.

Recent studies have concluded that different water bodies in the ocean can contain different microbial communities. The goal of the present study was to determine if biogeographic patterns are present for aquatic microbes in waters which meet around the South Shetland Islands(SSI), Antarctica. Prokaryotic and eukaryotic marine microbial communities were monitored during the 2007 austral summer by use of polymerase chain reaction (PCR) and denaturing gradientgel electrophoresis (DGGE) of small subunit ribosomal DNA. Hydrographic properties, nutrients and chlorophyll a were also measured. There was an onshore to offshore gradient in temperature, salinity and iron concentration and a unimodal distribution of chlorophyll a concentration in rela-tion to the middle of this gradient that occurred near the SSI. The differences in microbial community structure among stations in the studied area were correlated with both geographical distance and environmental factors. For eukaryotes, the correlation was strongest for environment, where as it was strongest for geographical distance for the prokaryotes. Eukaryotic and prokaryotic community structures were highly correlated. Surface water from the Weddell Sea had a different community of eukaryotes than the water in the Antarctic Circumpolar Current in the Drake Passage, whereas the prokaryotic community was not significantly different. The area close to theSSI where the 2 water types mix had the highest chlorophyll concentration and significantly dif-ferent communities of eukaryotes and prokaryotes from both of the inflowing water types. These results suggest that the prokaryote community structure was more affected by productivity thanby environmental variables. KEY WORDS: Microbial biogeography. Microbial community. Natural iron enrichment. Southern Ocean.

During ship-based seabird surveys in the south Atlantic and Antarctica in the austral summers of 1994/95, 2009, 2010, 2011 and 2012, we documented at-sea distributions of Buller’s albatross (Thalassarche bulleri), Atlantic petrel (Pterodroma incerta), soft-plumaged petrel (Pterodroma mollis), Kerguelen petrel (Lugensa brevirostris) and great-winged petrel (Pterodroma macroptera). In some cases, sightings were considered as extralimital, but for other species updating their distributions in the literature seems warranted. Atlantic petrel, for example, has been regularly observed in the Drake Passage and north of the Antarctic Peninsula for about 30 years, but the distribution of this species has not been updated in the literature. The observations reported here will contribute to update the at-sea distributions of these species and to changes in their distributions. Keywords: Seabirds; Antarctica; South Atlantic Ocean; distribution.

Data pertaining to environmental conditions, sympagic (sea ice) microalgal dynamics and particle flux were collected before the spring ice break-up 2001 in Pierre Lejay Bay, adjacent to the Dumont d'Urville Station, Petrel Island, East Antarctica. An array of two multiple sediment traps and a current meter was deployed for five weeks, from 8 November to 6 December 2001. The sea-ice chlorophyll a and particulate organic carbon (POC) averaged 0.6 mg l−1 (30 mg m−2) and 20 mg l−1 (1 g m−2) near the coast. The POC export flux that reached a maximum of 79 mg m−2 d−1 during the study period was high compared to the one for the Weddell Sea. The flux was homogeneous from the surface to 47 m depth and increased sharply 33 days before the effective ice break-up. A north-western progressive vector of currents (i.e., Lagrangian drift) in the sub-ice surface waters was demonstrated. Bottom ice, platelet ice and under-ice water at 5 m were characterized by differences in colonization and short-term succession of microalgae. Keywords: Land-fast ice; oceanic short-term regime; POM flux; sympagic communities; East Antarctica.