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In this reported study, a novel high-performance thin-layer chromatography (HPTLC) method was developed for the detection and quantification of the toxic substance di(2-ethylhexyl) adipate (DEHA) in Antarctic krill. This procedure was based on the extraction of DEHA by ultrasonic solvent extraction with anhydrous ethanol, silica-gel column chromatographic separation, HPTLC detection and quantification using petroleum ether/ethyl acetate/ acetone/glacial acetic acid (29:1:0.5:2d*, v/v/v/v) as the developing solvent and bromine thymol blue solution as the chromogenic agent. The content of DEHA in freeze-dried Antarctic krill was found to be ca. 0.63 ± 0.05 mg/g. The structure of DEHA in the Antarctic krill was subsequently determined by gas chromatography–mass spectrometry (GC-MS) and infrared chromatography, which verified the presence of this compound in the krill. The HPTLC method exhibited excellent accuracy, with a recovery of 97.1–101.6% and good precision with a relative standard deviation of 2.47–4.90%. The DEHA in Antarctic krill oil was extracted by n-hexane and detected using the same method described above, which verified that DEHA was also present in krill oil at a concentration of ca. 2.16 ± 0.08 mg/g. The presence of DEHA in kill oil is very concerning because of its demonstrated harmful ecotoxicity, and since Antarctic krill is the key link in the food chain in the Antarctic coastal marine ecosystem. The adverse effects of DEHA on Antarctic krill and the source of DEHA will be explored in future research.

The Inverse Gaussian approximation of transit time distribution method (IG-TTD) is widely used to infer the anthropogenic carbon (Cant) concentration in the ocean from measurements of transient tracers such as chlorofluorocarbons (CFCs) and sulfur hexafluoride (SF6). Its accuracy relies on the validity of several assumptions, notably (i) a steady state ocean circulation, (ii) a prescribed age tracer saturation history, e.g., a constant 100% saturation, (iii) a prescribed constant degree of mixing in the ocean, (iv) a constant surface ocean air-sea CO2 disequilibrium with time, and (v) that preformed alkalinity can be sufficiently estimated by salinity or salinity and temperature. Here, these assumptions are evaluated using simulated “model-truth” of Cant. The results give the IG-TTD method a range of uncertainty from 7.8% to 13.6% (11.4 Pg C to 19.8 Pg C) due to above assumptions, which is about half of the uncertainty derived in previous model studies. Assumptions (ii), (iv) and (iii) are the three largest sources of uncertainties, accounting for 5.5%, 3.8% and 3.0%, respectively, while assumptions (i) and (v) only contribute about 0.6% and 0.7%. Regionally, the Southern Ocean contributes the largest uncertainty, of 7.8%, while the North Atlantic contributes about 1.3%. Our findings demonstrate that spatial-dependency of , and temporal changes in tracer saturation and air-sea CO2 disequilibrium have strong compensating effect on the estimated Cant. The values of these parameters should be quantified to reduce the uncertainty of IG-TTD; this is increasingly important under a changing ocean climate.

Detailed scanning electron microscopy (SEM) micro-texture and mineralogical analysis of lacustrine sediment recovered from Profound Lake (also known as Uruguay Lake), Antarctica, was conducted in the foreland area of the Collins Glacier, King George Island. Very coarse and coarse sand grade size fractions (2 mm – 600 μm) were examined with SEM/ energy dispersive spectrometry, while the total sand fraction and fines (silt + clay) were examined using x-ray diffraction to determine relationships to source rock, weathering and transport history and long-term clay mineral weathering, all of which are poorly understood in polar areas. The mineralogy of these sediments was compared with petrographical information of the country rock to identify potential detrital sources. The association of recovered detrital minerals, sometimes strongly pre-weathered, supports release from source rock of basaltic and andesitic compositions. The micro-texture analysis of quartz, magnetite and various plagioclase grains show micro-features that reveal a complex weathering–diagenesis history tentatively extending into the Paleogene. The bedrock was eroded mostly by glacial processes and mechanical action presumed to result from glacial crushing. Alteration minerals, likely the product of pre-weathering, are probably sourced from weathered bedrock during contact with the sub-aerial atmosphere prior to entrainment. However, amorphous silica precipitation indicates weathering subsequent to glacial erosion from the source bedrock. Cracks of variable dimensions are mostly characteristic of either frost weathering or glacial transport, and involve mechanical and chemical processes.

The Antarctic has significant environmental, scientific, historic, and intrinsic values, all of which are worth protecting into the future. Nevertheless, the area is subject to an increasing level and diversity of human activities that may impact these values within marine, terrestrial and cryosphere environments. Threats to the Antarctic environment, and to the aforementioned values, include climate change, pollution, habitat destruction, wildlife disturbance and non-native species introductions. Over time, a suite of legally binding international agreements, which form part of the Antarctic Treaty System (ATS), has been established to help safeguard the Antarctic environment and provide a framework for addressing the challenges arising from these threats. Foremost among these agreements are the Protocol on Environmental Protection to the Antarctic Treaty and the Convention on the Conservation of Antarctic Marine Living Resources. Many scientists working in Antarctica undertake research that is relevant to Antarctic environmental policy development. More effective two-way interaction between scientists and those responsible for policy development would further strengthen the governance framework, including by (a) better communication of policy makers’ priorities and identification of related science requirements and (b) better provision by scientists of ‘policy-ready’ information on existing priorities, emerging issues and scientific/technological advances relevant to environmental protection. The Scientific Committee on Antarctic Research (SCAR) has a long and successful record of summarizing policy-relevant scientific knowledge to policy makers, such as through its Group of Specialists on Environmental Affairs and Conservation (GOSEAC) up to 2002, currently the SCAR Standing Committee on the Antarctic Treaty System (SCATS) and recently through its involvement in the Antarctic Environments Portal. Improvements to science-policy communication mechanisms, combined with purposeful consideration of funding opportunities for policy-relevant science, would greatly enhance international policy development and protection of the Antarctic environment.

Antarctica’s terrestrial ecosystems are vulnerable to impacts resulting from climate change and local human activities. The Antarctic Treaty System (ATS) provides for the designation of protected areas through the Protocol on Environmental Protection to the Antarctic Treaty. Unsystematic use of agreed management tools, including Antarctic Specially Protected Areas (ASPAs), has resulted in a protected area system lacking representation across the full range of Antarctic terrestrial ecosystems and Antarctic Conservation Biogeographic Regions (ACBRs). Systematic Conservation Planning (SCP) methods provide established mechanisms to fulfil ATS protected area designation goals. However, how would a continent-wide ASPA system be delivered should appropriate sites be identified using SCP or other methods? Although the rate of area protection has slowed recently, we show that newer Consultative Parties to the Antarctic Treaty are increasingly active as ASPA proponents and may have scope for further engagement with protected area management activities. Furthermore, all 16 ACBRs were found to be within the operational footprint of at least two Parties, indicating that this current logistical footprint could support the implementation and management of a continent-wide ASPA system. Effective management of a representative Antarctic protected areas system could be delivered through greater participation by those Parties with currently more limited protected area management responsibilities and greater use of remote-sensing technologies for protected area monitoring, where appropriate. Crucially, political will to implement an ASPA system identified through SCP approaches may be greater once a pragmatic means of delivery and effective management has been identified.

A climatically induced acceleration in ocean-driven melting of Antarctic ice shelves would have consequences for both the discharge of continental ice into the ocean and thus global sea level, and for the formation of Antarctic Bottom Water and the oceanic meridional overturning circulation. Using a novel gas-tight in situ water sampler, noble gas samples have been collected from six locations beneath the Filchner Ice Shelf, the first such samples from beneath an Antarctic ice shelf. Helium and neon are uniquely suited as tracers of glacial meltwater in the ocean. Basal meltwater fractions range from 3.6% near the ice shelf base to 0.5% near the sea floor, with distinct regional differences. We estimate an average basal melt rate for the Filchner-Ronne Ice Shelf of 177 ± 95 Gt/year, independently confirming previous results. We calculate that up to 2.7% of the meltwater has been refrozen, and we identify a local source of crustal helium.

One of the great challenges in glaciology is the ability to estimate the bulk ice anisotropy in ice sheets and glaciers, which is needed to improve our understanding of ice-sheet dynamics. We investigate the effect of crystal anisotropy on seismic velocities in glacier ice and revisit the framework which is based on fabric eigenvalues to derive approximate seismic velocities by exploiting the assumed symmetry. In contrast to previous studies, we calculate the seismic velocities using the exact c axis angles describing the orientations of the crystal ensemble in an ice-core sample. We apply this approach to fabric data sets from an alpine and a polar ice core. Our results provide a quantitative evaluation of the earlier approximative eigenvalue framework. For near-vertical incidence our results differ by up to 135 m s−1 for P-wave and 200 m s−1 for S-wave velocity compared to the earlier framework (estimated 1 % difference in average P-wave velocity at the bedrock for the short alpine ice core). We quantify the influence of shear-wave splitting at the bedrock as 45 m s−1 for the alpine ice core and 59 m s−1 for the polar ice core. At non-vertical incidence we obtain differences of up to 185 m s−1 for P-wave and 280 m s−1 for S-wave velocities. Additionally, our findings highlight the variation in seismic velocity at non-vertical incidence as a function of the horizontal azimuth of the seismic plane, which can be significant for non-symmetric orientation distributions and results in a strong azimuth-dependent shear-wave splitting of max. 281 m s−1 at some depths. For a given incidence angle and depth we estimated changes in phase velocity of almost 200 m s−1 for P wave and more than 200 m s−1 for S wave and shear-wave splitting under a rotating seismic plane. We assess for the first time the change in seismic anisotropy that can be expected on a short spatial (vertical) scale in a glacier due to strong variability in crystal-orientation fabric (±50 m s−1 per 10 cm). Our investigation of seismic anisotropy based on ice-core data contributes to advancing the interpretation of seismic data, with respect to extracting bulk information about crystal anisotropy, without having to drill an ice core and with special regard to future applications employing ultrasonic sounding.

We carried out a bibliometric analysis of literature related to glaciers in polar regions from the period 1987–2016 indexed in the Science Citation Index Expanded database. A comprehensive review was performed by analysing the research output trends, publication categories, main journals, leading countries and their collaborations, leading scientists, author keywords and Keywords Plus. The results indicated that the number of publications related to glaciers in polar regions has increased rapidly. The USA and several European countries, including the UK, France, Germany and Switzerland, are the leaders in the field of glacial studies, as reflected both in the productivity measures and in the distribution of core scientists. Quaternary Science Reviews, the Journal of Glaciology, and Geophysical Research Letters were the most productive journals for glacial studies. The synthesized analysis of the keywords demonstrated the current research emphases and hinted at future research trends. Reconstructing past climate changes through studies of ice-core records is one of the most important research subjects. Numerical modelling has become a commonly used tool in polar region glacial research. A better understanding of the responses of glaciers to widespread climatic warming is needed now and in the future.

There is increasing interest in using higher-trophic level predators as ecosystem indicators because their performance is presumed to be linked to the overall function of the ecosystem that supports them. In the southwest Atlantic sector of the Southern Ocean, Antarctic krill (Euphausia superba) supports huge predator populations as well as a growing commercial fishery. To utilize information from the ecosystem in an adaptive framework for sustainably managing krill catch levels, performance indices of krill predators have been proposed as a proxy for krill abundance. However, there are several potentially confounding sources of variability that might impact predator performance such as the effects of environmental variability and fishing pressure on krill availability at scales relevant to predators. In this context, our study capitalises on the occurrence of an unexpected El Niño event to characterise how environmental variability can drive changes in predator foraging behaviour. We demonstrate a clear link between coastal downwelling and changes in the at-sea habitat usage of chinstrap penguins (Pygoscelis antarctica) foraging in a local krill fishing area. Penguins tracked from their breeding colonies on Powell Island, Antarctic Peninsula, undertook fewer, longer foraging trips during the downwelling-affected season compared with the season where no such downwelling was detected, suggesting that changes in climate-driven oceanography may have reduced krill availability along the northern shelf of the island. Our study demonstrates that penguin foraging behaviour is modified by scale-dependent processes, which if not accounted for may result in erroneous conclusions being drawn when using penguins as bioindicators of krill abundance.

By virtue of the Antarctic Treaty, signed in 1959, the territorial claims to Antarctica of seven of the original signatories were held in abeyance or “frozen.” Considered by many as an exemplar of international law, the Antarctic Treaty System has come to be increasingly questioned, however, in a very much changed global scenario that presents new challenges to the governance of the White Continent. In this context, it is necessary to gain a clearer understanding of the moral weight of those initial claims, which stand (despite being frozen) as a cornerstone of the treaty. The aim of this article is to offer an appraisal of such claims, which may be divided into two main kinds: those grounded on some relevant link to the territory, and those grounded on official documents and geographical doctrines. After pointing to the limitations and challenges that they face, I conclude with some remarks about how this assessment ought to serve as a starting point to rethink the territorial status of Antarctica.

A likely important feature of the poorly understood aerosol-cloud interactions over the Southern Ocean (SO) is the dominant role of sea spray aerosol, versus terrestrial aerosol. Ice nucleating particles (INPs), or particles required for heterogeneous ice nucleation, present over the SO have not been studied in several decades. In this study, boundary layer aerosol properties and immersion freezing INP number concentrations (nINPs) were measured during a ship campaign that occurred south of Australia (down to 53°S) in March–April 2016. Ocean surface chlorophyll a concentrations ranged from 0.11 to 1.77 mg/m3, and nINPs were a factor of 100 lower than historical surveys, ranging from 0.38 to 4.6 m−3 at −20 °C. The INP population included organic heat-stable material, with contributions from heat-labile material. Lower INP source potentials of SO seawater samples compared to Arctic seawater were consistent with lower ice nucleating site densities in this study compared to north Atlantic air masses.

The contribution of oceanic net community production (NCP) to the observed seasonal cycle in atmospheric potential oxygen (APO) is estimated at Cape Grim, Tasmania. The resulting APONCP signal is compared to satellite and ocean model-based estimates of POC export and NCP across the Southern Ocean. The satellite products underestimate the amplitude of the observed APONCP seasonal cycle by more than a factor of 2. Ocean models suggest two reasons for this underestimate: (1) Current satellite products substantially underestimate the magnitude of NCP in early spring. (2) Seasonal O2 outgassing is supported in large part by storage of carbon in DOC and living biomass. More DOC observations are needed to help evaluate this latter model prediction. Satellite products could be improved by developing seasonally dependent relationships between remote sensing chlorophyll data and in situ NCP, recognizing that the former is a measure of mass, the latter of flux.

While observed mesospheric polar nitric acid enhancements have been attributed to energetic particle precipitation through ion cluster chemistry in the past, this phenomenon is not reproduced in current whole-atmosphere chemistry-climate models. We investigate such nitric acid enhancements resulting from energetic electron precipitation events using a recently developed variant of the Whole Atmosphere Community Climate Model (WACCM) that includes a sophisticated ion chemistry tailored for the D-layer of the ionosphere (50–90 km), namely, WACCM-D. Using the specified dynamics mode, that is, nudging dynamics in the troposphere and stratosphere to meteorological reanalyses, we perform a 1-year-long simulation (July 2009–June 2010) and contrast WACCM-D with the standard WACCM. Both WACCM and WACCM-D simulations are performed with and without forcing from medium-to-high energy electron precipitation, allowing a better representation of the energetic electrons penetrating into the mesosphere. We demonstrate the effects of the strong particle precipitation events which occurred during April and May 2010 on nitric acid and on key ion cluster species, as well as other relevant species of the nitrogen family. The 1-year-long simulation allows the event-related changes in neutral and ionic species to be placed in the context of their annual cycle. We especially highlight the role played by medium-to-high energy electrons in triggering ion cluster chemistry and ion-ion recombinations in the mesosphere and lower thermosphere during the precipitation event, leading to enhanced production of nitric acid and raising its abundance by 2 orders of magnitude from 10−4 to a few 10−2 ppb.

Isen i Antarktis smelter ikkje med det første, men store endringar er undervegs i havet. Havvatnet rundt Antarktis er iskaldt, men nå observerer vi at varmare vatn strøymer innunder den flytande delen av is-kappen. Om denne utviklinga ikkje stopper vil meir innlandsis strøyme ut i havet og føre til at havnivået vil stige med fleire meter. Det er langt frå sikkert at dette vil skje, men det er eit veldig viktig klimaspørsmål som vi må forstå betre. Difor har Uni Research med støtte av Forskingsrådet og Polarinstituttet bygd fleire havobservatorium for å kunne gi eit tidleg varsel dramatisk endringar.

The multi-temporal scales of two physical characteristics (areas and occurrence time) of the Ross Sea Polynya (RSP) in Antarctica were analysed using a sea-ice concentration data set (1979–2014) derived from the Scanning Multichannel Microwave Radiometer, the Special Sensor Microwave Imager and Sensor Microwave Imager Sounder. Then, the Ensemble Empirical Mode Decomposition (EEMD) was applied to the data sets to decompose signals into finite numbers of intrinsic mode functions and a residual mode: long time trend. This approach allowed us to understand the long-term variability of the RSP area and occurrence in response to atmospheric forcing through teleconnections between low and high latitudes by comparing the Nino3.4 and Southern Annular Mode (SAM) indices. The nonlinear trend of the RSP areas derived from the EEMD residual had an upward trending shift in the early 1990s and was fairly consistent with the nonlinear trend of Nino3.4. However, the trend of RSP occurrence time progressively increased and had a significant effect on the long time scale. The trend of the RSP area is significantly correlated (+0.98) with the ratio of the trend of the meridional to zonal wind components related with the nonlinearity of Nino3.4, suggesting that meridional wind stress dominated the changes of the polynya area in the Ross Sea. In addition, the nonlinear trends between the SAM and RSP occurrence time show a strong positive correlation, contributing to the earlier onset of polynya expansion and delayed connection with the open ocean owing to enhanced southerly winds.

During the 35th Indian Scientific Expedition to Antarctica, measurements of atmospheric carbon dioxide (CO 2 ) were carried out using a Li-Cor CO 2 /H 2 O analyser at Bharati, the Indian Antarctic research station. This study examines the short-term variability of atmospheric CO 2 during the austral summer (January–February) of 2016. An average of 396.25 ± 4.20 ppm was observed during the study period. Meteorological parameters such as relative humidity, precipitation, wind speed, air temperature and atmospheric boundary layer height in conjunction with photosynthetically active radiation, the biological activity indicator which modulates atmospheric CO 2 concentration have been investigated. High wind speed (>20 m s −1 ) combined with precipitation scavenges CO 2 in the atmosphere, resulting in low concentrations at the study site. The lowest CO 2 concentration of 385 ppm coincided with heavy precipitation of 15 mm during study period. Statistical analysis of the data shows that precipitation and relative humidity independently correlated 55% (r = −0.55) and 32% (r = −0.32), respectively, with the variability of CO 2 mixing in the atmosphere at the study site. Atmospheric CO 2 was significantly correlated with precipitation alone with a p value of 0.003. Further, multiple regression analysis was performed to test the significant relation between variability of atmospheric CO 2 and meteorological parameters. Long-range air-mass transport analysis depicted that the majority of the air masses are reaching the study site through the oceanic region.

This study aims to describe the planktonic food web structure with respect to phytoplankton biomass (chlorophyll a ) and prevailing environmental conditions at the South Subtropical Front (SSTF) and the Polar Front (PF) in the Indian sector of the Southern Ocean. Sampling was carried out at each front for 72 hrs, at 6-hr intervals, during the austral summer 2011. Considerable variations were observed in the hydrography between these two fronts. A strong temperature minimum layer was observed at the PF. Although the surface primary production and chlorophyll a values showed similar trends at both the fronts, the water column values of these parameters showed major disparities. The phytoplankton composition also revealed marked difference between the fronts. A deep chlorophyll maximum concordant with the upper limit of the temperature minimum layer was prominent at the PF. The microzooplankton abundance at the SSTF was twice as high as at the PF. The mesozooplankton biovolume and population density also showed considerable variations between these fronts. Noticeable diel variations were observed in the surface mesozooplankton biovolumes at both the fronts and the copepod Pleuromamma gracilis showed active diel vertical migration at SSTF. Both the grazing and senescence indices showed significant variations between these fronts, suggesting a disparity in the ecological efficiency of the two regions. The variability observed in the plankton community structure with respect to the hydrography and the biological components measured suggests that a multivorous food web at the SSTF and a conventional food web at the PF prevailed during the period of study.