Your search

An evaluation is made of ozone profiles retrieved from measurements of the nadir-viewing Global Ozone Monitoring Experiment (GOME) instrument. Currently, four different approaches are used to retrieve ozone profile information from GOME measurements, which differ in the use of external information and a priori constraints. In total nine different algorithms will be evaluated exploiting the optimal estimation (Royal Netherlands Meteorological Institute, Rutherford Appleton Laboratory, University of Bremen, National Oceanic and Atmospheric Administration, Smithsonian Astrophysical Observatory), Phillips-Tikhonov regularization (Space Research Organization Netherlands), neural network (Center for Solar Energy and Hydrogen Research, Tor Vergata University), and data assimilation (German Aerospace Center) approaches. Analysis tools are used to interpret data sets that provide averaging kernels. In the interpretation of these data, the focus is on the vertical resolution, the indicative altitude of the retrieved value, and the fraction of a priori information. The evaluation is completed with a comparison of the results to lidar data from the Network for Detection of Stratospheric Change stations in Andoya (Norway), Observatoire Haute Provence (France), Mauna Loa (Hawaii), Lauder (New Zealand), and Dumont d'Urville (Antarctic) for the years 1997–1999. In total, the comparison involves nearly 1000 ozone profiles and allows the analysis of GOME data measured in different global regions and hence observational circumstances. The main conclusion of this paper is that unambiguous information on the ozone profile can at best be retrieved in the altitude range 15–48 km with a vertical resolution of 10 to 15 km, precision of 5–10%, and a bias up to 5% or 20% depending on the success of recalibration of the input spectra. The sensitivity of retrievals to ozone at lower altitudes varies from scheme to scheme and includes significant influence from a priori assumptions.

A solar occultation sensor, the Improved Limb Atmospheric Spectrometer (ILAS)-II, measured 5890 vertical profiles of ozone concentrations in the stratosphere and lower mesosphere and of other species from January to October 2003. The measurement latitude coverage was 54–71°N and 64–88°S, which is similar to the coverage of ILAS (November 1996 to June 1997). One purpose of the ILAS-II measurements was to continue such high-latitude measurements of ozone and its related chemical species in order to help accurately determine their trends. The present paper assesses the quality of ozone data in the version 1.4 retrieval algorithm, through comparisons with results obtained from comprehensive ozonesonde measurements and four satellite-borne solar occultation sensors. In the Northern Hemisphere (NH), the ILAS-II ozone data agree with the other data within ±10% (in terms of the absolute difference divided by its mean value) at altitudes between 11 and 40 km, with the median coincident ILAS-II profiles being systematically up to 10% higher below 20 km and up to 10% lower between 21 and 40 km after screening possible suspicious retrievals. Above 41 km, the negative bias between the NH ILAS-II ozone data and the other data increases with increasing altitude and reaches 30% at 61–65 km. In the Southern Hemisphere, the ILAS-II ozone data agree with the other data within ±10% in the altitude range of 11–60 km, with the median coincident profiles being on average up to 10% higher below 20 km and up to 10% lower above 20 km. Considering the accuracy of the other data used for this comparative study, the version 1.4 ozone data are suitably used for quantitative analyses in the high-latitude stratosphere in both the Northern and Southern Hemisphere and in the lower mesosphere in the Southern Hemisphere.

The 2002 Southern Hemisphere final warming occurred early, following an unusually active winter and the first recorded major warming in the Antarctic. The breakdown of the stratospheric polar vortex in October and November 2002 is examined using new satellite observations from the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) instrument aboard the European Space Agency (ESA) Environment Satellite (ENVISA7-) and meteorological analyses, both high-resolution fields from the European Centre for Medium-Rangc Weather Forecasts and the coarser Met Office analyses. The results derived from MIPAS observations are compared to measurements and inferences from well-validated solar occultation satellite instruments [Halogen Occultation Experiment (HALOE), Polar Ozone and Aerosol Measurement lit (POAM III), and Stratospheric Aerosol and Gas Experiments II and III (SAGE II and III)] and to finescale tracer fields reconstructed by transporting trace gases based oil MIPAS or climatological data using a reverse-trajectory method. These comparisons confirm the features in the MIPAS data and the interpretation of the evolution of the flow during the vortex decay revealed by those features. Mapped ozone and water vapor from MIPAS and the analyzed isentropic potential vorticity vividly display the vortex breakdown, which occurred earlier than usual. A large tongue of vortex air was pulled out westward and coiled up in an anticyclone, while the vortex core remnant shrank and drifted eastward and equatorward over the South Atlantic. By roughly mid-November, the vortex remnant at 10 mb had shrunk below scales resolved by the satellite observations, while a vortex core remained in the lower stratosphere.

In March 2002 the European Space Agency (ESA) launched the polar-orbiting environmental satellite Envisat. One of its nine instruments is the Global Ozone Monitoring by Occultation of Stars (GOMOS) instrument, which is a medium-resolution stellar occultation spectrometer measuring vertical profiles of ozone. In the first year after launch a large group of scientists performed additional measurements and validation activities to assess the quality of Envisat observations. In this paper, we present validation results of GOMOS ozone profiles from comparisons to microwave radiometer, balloon ozonesonde, and lidar measurements worldwide. Thirty-one instruments/launch sites at twenty-five stations ranging from the Arctic to the Antarctic joined in this activity. We identified 6747 collocated observations that were performed within an 800-km radius and a maximum 20-hour time difference of a satellite observation, for the period between 1 July 2002 and 1 April 2003. The GOMOS data analyzed here have been generated with a prototype processor that corresponds to version 4.02 of the operational GOMOS processor. The GOMOS data initially contained many obviously unrealistic values, most of which were successfully removed by imposing data quality criteria. Analyzing the effect of these criteria indicated, among other things, that for some specific stars, only less than 10% of their occultations yield an acceptable profile. The total number of useful collocated observations was reduced to 2502 because of GOMOS data unavailability, the imposed data quality criteria, and lack of altitude overlap. These collocated profiles were compared, and the results were analyzed for possible dependencies on several geophysical (e.g., latitude) and GOMOS observational (e.g., star characteristics) parameters. We find that GOMOS data quality is strongly dependent on the illumination of the limb through which the star is observed. Data measured under bright limb conditions, and to a certain extent also in twilight limb, should be used with caution, as their usability is doubtful. In dark limb the GOMOS data agree very well with the correlative data, and between 14- and 64-km altitude their differences only show a small (2.5–7.5%) insignificant negative bias with a standard deviation of 11–16% (19–63 km). This conclusion was demonstrated to be independent of the star temperature and magnitude and the latitudinal region of the GOMOS observation, with the exception of a slightly larger bias in the polar regions at altitudes between 35 and 45 km.

To improve our understanding of wintertime polar ozone losses, two ozonesonde Match campaigns were performed. The first one was carried out in the Arctic winter 2002/03. About 450 coordinated ozonesondes were launched from late November 2002 to March 2003. Temperatures low enough for the formation of polar stratospheric clouds (PSC) occurred already in the second half of November. At 475 K the Match analysis shows increasing ozone loss rates from early December until the second half of January with peaking loss rates of 35 ppbv/day. Afterwards the rate of ozone loss decreased and stopped after a month. Throughout the whole winter we find accumulated ozone loss of about 1.5 ppmv at the 500 K isentrope and approximately 60 DU in the total ozone column, which is about half of the maximum loss found in past winters. From June to October 2003 an Antarctic Match campaign was carried out for the first time. About 400 sondes were launched by 9 stations. Ozone loss rates of up to 75 ppbv/day were found inside the polar vortex at the 475 K potential temperature level during the first half of September. The timing of the fastest ozone loss coincides with the return of sunlight to the vortex after the Antarctic winter. During the whole time period temperatures were low enough for PSCs, including ice clouds, to form. Results for the potential temperature range between 400 K and 550 K will be presented.

Ground-based zenith sky UV–visible measurements of stratospheric bromine monoxide (BrO) slant column densities are compared with simulations from the SLIMCAT three-dimensional chemical transport model. The observations have been obtained from a network of 11 sites, covering high and midlatitudes of both hemispheres. This data set gives for the first time a near-global picture of the distribution of stratospheric BrO from ground-based observations and is used to test our current understanding of stratospheric bromine chemistry. In order to allow a direct comparison between observations and model calculations, a radiative transfer model has been coupled to the chemical model to calculate simulated slant column densities. The model reproduces the observations in general very well. The absolute amount of the BrO slant columns is consistent with a total stratospheric bromine loading of 20 ± 4 ppt for the period 1998–2000, in agreement with previous estimates. The seasonal and latitudinal variations of BrO are well reproduced by the model. In particular, the good agreement between the observed and modeled diurnal variation provides strong evidence that the BrO-related bromine chemistry is correctly modeled. A discrepancy between observed and modeled BrO at high latitudes during events of chlorine activation can be resolved by increasing the rate constant for the reaction BrO + ClO → BrCl + O2 to the upper limit of current recommendations. However, other possible causes of the discrepancy at high latitudes cannot be ruled out.

The altitude dependent variability of ozone in the polar stratosphere is regularly observed by balloon-borne ozonesonde observations at Neumayer Station (70°S) in the Antarctic and at Koldewey Station (79°N) in the Arctic. The reasons for observed seasonal and interannual variability and long-term changes are discussed. Differences between the hemispheres are identified and discussed in light of differing dynamical and chemical conditions. Since the mid- 1980s, rapid chemical ozone loss has been recorded in the lower Antarctic stratosphere during the spring season. Using coordinated ozone soundings in some Arctic winters, similar chemical ozone loss rates have been detected related to periods of low temperatures. The currently observed cooling trend of the stratosphere, potentially caused by the increase of anthropogenic greenhouse gases, may further strengthen chemical ozone removal in the Arctic. However, the role of internal climate oscillations in observed temperature trends is still uncertain. First results of a 10000 year integration of a low order climate model indicate significant internal climate variability. on decadal time scales, that may alter the effect of increasing levels of greenhouse gases in the polar stratosphere.