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Enhancement of ocean alkalinity using calcium compounds, e.g., lime has been proposed to mitigate further increase of atmospheric CO2 and ocean acidification due to anthropogenic CO2 emissions. Using a global model, we show that such alkalinization has the potential to preserve pH and the saturation state of carbonate minerals at close to today's values. Effects of alkalinization persist after termination: Atmospheric CO2 and pH do not return to unmitigated levels. Only scenarios in which large amounts of alkalinity (i.e., in a ratio of 2:1 with respect to emitted CO2) are added over large ocean areas can boost oceanic CO2 uptake sufficiently to avoid further ocean acidification on the global scale, thereby elevating some key biogeochemical parameters, e.g., pH significantly above preindustrial levels. Smaller-scale alkalinization could counteract ocean acidification on a subregional or even local scale, e.g., in upwelling systems. The decrease of atmospheric CO2 would then be a small side effect.

We have examined changes in climate which result from the sudden termination of geoengineering after 50 years of offsetting a 1% per annum increase in CO2 concentrations by a reduction of solar radiation, as simulated by 11 different climate models in experiment G2 of the Geoengineering Model Intercomparison Project. The models agree on a rapid increase in global-mean temperature following termination accompanied by increases in global-mean precipitation rate and decreases in sea-ice cover. There is no agreement on the impact of geoengineering termination on the rate of change of global-mean plant net primary productivity. There is a considerable degree of consensus for the geographical distribution of temperature change following termination, with faster warming at high latitudes and over land. There is also considerable agreement regarding the distribution of reductions in Arctic sea-ice, but less so for the Antarctic. There is much less agreement regarding the patterns of change in precipitation and net primary productivity, with a greater degree of consensus at higher latitudes.

Enhanced snowfall on the East Antarctic ice sheet is projected to significantly mitigate 21st century global sea level rise. In recent years (2009 and 2011), regionally extreme snowfall anomalies in Dronning Maud Land, in the Atlantic sector of East Antarctica, have been observed. It has been unclear, however, whether these anomalies can be ascribed to natural decadal variability, or whether they could signal the beginning of a long-term increase of snowfall. Here we use output of a regional atmospheric climate model, evaluated with available firn core records and gravimetry observations, and show that such episodes had not been seen previously in the satellite climate data era (1979). Comparisons with historical data that originate from firn cores, one with records extending back to the 18th century, confirm that accumulation anomalies of this scale have not occurred in the past ~60 years, although comparable anomalies are found further back in time. We examined several regional climate model projections, describing various warming scenarios into the 21st century. Anomalies with magnitudes similar to the recently observed ones were not present in the model output for the current climate, but were found increasingly probable toward the end of the 21st century.

In this study, we present evidence that Antarctic and Arctic sea ice act as sink for atmospheric CO2 during periods of snowmelt and surface flooding. The CO2 flux measured directly at the flooded sea ice surface (Fflood) constituted a net CO2 sink of −1.1 ± 0.9 mmol C m−2 d−1 (mean ± 1 SD), which was an order of magnitude higher than the flux measured at the snow-air surface (Fsnow) and bare ice surface (Fice). The Fsnow/Fflood ratio decreased with increasing water equivalent of snow and superimposed-ice, suggesting that the properties of snow and superimposed-ice formation affect the magnitude of the CO2 flux. The Fsnow/Fflood ratio ranged from 0.1 to 0.5, illustrating that 50–90% of the potential flux at the flooded surface was reduced due to the presence of snow/superimposed-ice. Hence, snow cover properties and superimposed-ice play an important role in the CO2 fluxes across the sea ice-snow-atmosphere interface.

Over the last decade, several hundred seals have been equipped with conductivity-temperature-depth sensors in the Southern Ocean for both biological and physical oceanographic studies. A calibrated collection of seal-derived hydrographic data is now available, consisting of more than 165,000 profiles. The value of these hydrographic data within the existing Southern Ocean observing system is demonstrated herein by conducting two state estimation experiments, differing only in the use or not of seal data to constrain the system. Including seal-derived data substantially modifies the estimated surface mixed-layer properties and circulation patterns within and south of the Antarctic Circumpolar Current. Agreement with independent satellite observations of sea ice concentration is improved, especially along the East Antarctic shelf. Instrumented animals efficiently reduce a critical observational gap, and their contribution to monitoring polar climate variability will continue to grow as data accuracy and spatial coverage increase.

The spatiotemporal sensitivity of Antarctic sea ice season length trends are examined using satellite-derived observations over 1979–2012. While the large-scale spatial structure of multidecadal trends has varied little during the satellite record, the magnitude of trends has undergone substantial weakening over the past decade. This weakening is particularly evident in the Ross and Bellingshausen Seas, where a ∼25–50% reduction is observed when comparing trends calculated over 1979–2012 and 1979–1999. Multidecadal trends in the Bellingshausen Sea are found to be dominated by variability over subdecadal time scales, particularly the rapid decline in season length observed between 1979 and 1989. In fact, virtually no trend is detectable when the first decade is excluded from trend calculations. In contrast, the sea ice expansion in the Ross Sea is less influenced by shorter-term variability, with trends shown to be more consistent at decadal time scales and beyond. Understanding these contrasting characteristics have implications for sea ice trend attribution.

Many challenges remain for estimating the Antarctic ice sheet surface mass balance (SMB), which represents a major uncertainty in predictions of future sea-level rise. Validating continental scale studies is hampered by the sparse distribution of in situ data. Here we present a 26 year mean SMB of the Fimbul ice shelf in East Antarctica between 1983–2009, and recent interannual variability since 2010. We compare these data to the results of large-scale SMB studies for similar time periods, obtained from regional atmospheric modeling and remote sensing. Our in situ data include ground penetrating radar, firn cores, and mass balance stakes and provide information on both temporal and spatial scales. The 26 year mean SMB on the Fimbul ice shelf varies between 170 and 620 kg m−2 a−1 giving a regional average value of 310 ± 70 kg m−2 a−1. Our measurements indicate higher long-term accumulation over large parts of the ice shelf compared to the large-scale studies. We also show that the variability of the mean annual SMB, which can be up to 90%, can be a dominant factor in short-term estimates. The results emphasize the importance of using a combination of ground-based validation data, regional climate models, and remote sensing over a relevant time period in order to achieve a reliable SMB for Antarctica.