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Microplastic (MP; plastic particles < 5 mm) pollution is pervasive in the marine environment, including remote polar environments. This study provides the first pan-Antarctic survey of MP pollution in Southern Ocean sea ice by analyzing sea ice cores from several diverse Antarctic regions. Abundance, chemical composition, and particle size data were obtained from 19 archived ice core samples. The cores were melted, filtered, and chemically analyzed using Fourier-transform infrared spectroscopy and 4,090 MP particles were identified. Nineteen polymer types were found across all samples, with an average concentration of 44.8 (± 50.9) particles·L-1. Abundance and composition varied with ice type and geographical location. Pack ice exhibited significantly higher particle concentrations than landfast ice, suggesting open ocean sources of pollution. Winter sea ice cores had significantly more MPs than spring and summer-drilled cores, suggesting ice formation processes play a role in particle incorporation. Smaller particles dominated across samples. Polyethylene (PE) and polypropylene (PP) were the most common polymers, mirroring those most identified across marine habitats. Higher average MP concentrations in developing sea ice during autumn and winter, contrasting lower levels observed in spring and summer, suggest turbulent conditions and faster growth rates are likely responsible for the increased incorporation of particles. Southern Ocean MP contamination likely stems from both local and distant sources. However, the circulation of deep waters and long-range transport likely contribute to the accumulation of MPs in regional gyres, coastlines, and their eventual incorporation into sea ice. Additionally, seasonal sea ice variations likely influence regional polymer compositions, reflecting the MP composition of the underlying waters.

New Zealand was among the last habitable places on earth to be colonized by humans. Charcoal records indicate that wildfires were rare prior to colonization and widespread following the 13th- to 14th-century Māori settlement, but the precise timing and magnitude of associated biomass-burning emissions are unknown, as are effects on light-absorbing black carbon aerosol concentrations over the pristine Southern Ocean and Antarctica. Here we used an array of well-dated Antarctic ice-core records to show that while black carbon deposition rates were stable over continental Antarctica during the past two millennia, they were approximately threefold higher over the northern Antarctic Peninsula during the past 700 years. Aerosol modelling demonstrates that the observed deposition could result only from increased emissions poleward of 40° S—implicating fires in Tasmania, New Zealand and Patagonia—but only New Zealand palaeofire records indicate coincident increases. Rapid deposition increases started in 1297 (±30 s.d.) in the northern Antarctic Peninsula, consistent with the late 13th-century Māori settlement and New Zealand black carbon emissions of 36 (±21 2 s.d.) Gg y−1 during peak deposition in the 16th century. While charcoal and pollen records suggest earlier, climate-modulated burning in Tasmania and southern Patagonia, deposition in Antarctica shows that black carbon emissions from burning in New Zealand dwarfed other preindustrial emissions in these regions during the past 2,000 years, providing clear evidence of large-scale environmental effects associated with early human activities across the remote Southern Hemisphere.

Understanding climate proxy records that preserve physical characteristics of past climate is a prerequisite to reconstruct long-term climatic conditions. Water stable isotope ratios (δ18O) constitute a widely used proxy in ice cores to reconstruct temperature and climate. However, the original climate signal is altered between the formation of precipitation and the ice, especially in low-accumulation areas such as the East Antarctic Plateau. Atmospheric conditions under which the isotopic signal is acquired at Aurora Basin North (ABN), East Antarctica, are characterized with the regional atmospheric model Modèle Atmosphérique Régional (MAR). The model shows that 50% of the snow is accumulated in less than 24 days year−1. Snowfall occurs throughout the year and intensifies during winter, with 64% of total accumulation between April and September, leading to a cold bias of −0.86°C in temperatures above inversion compared to the annual mean of −29.7°C. Large snowfall events are associated with high-pressure systems forcing warm oceanic air masses toward the Antarctic interior, which causes a warm bias of +2.83°C. The temperature-δ18O relationship, assessed with the global atmospheric model ECHAM5-wiso, is primarily constrained by the winter variability, but the observed slope is valid year-round. Three snow δ18O records covering 2004–2014 indicate that the anomalies recorded in the ice core are attributable to the occurrence of warm winter storms bringing precipitation to ABN and support the interpretation of δ18O in this region as a marker of temperature changes related to large-scale atmospheric conditions, particularly blocking events and variations in the Southern Annular Mode.

In central Antarctica, where accumulation rates are very low, summer sublimation of surface snow is a key element of the surface mass balance, but its fingerprint in isotopic composition of water (δD, δ18O, and δ17O) remains unclear. In this study, we examined the influence of summer sublimation on δD, δ18O, and δ17O in precipitation using data sets of isotopic composition of precipitation at various sites on the inland East Antarctica. We found unexpectedly low δ18O values in the summer precipitation, decoupled from surface air temperatures. This feature can be explained by the combined effects of weak or nonexistent temperature inversion and moisture recycling associated with sublimation-condensation processes in summer. Isotopic fractionation during the moisture-recycling process also explains the observed high values of d-excess and 17O-excess in summer precipitation. Our results suggest that the local cycle of sublimation-condensation in summer is an important process for the isotopic composition of surface snow, water vapor, and consequently precipitation on inland East Antarctica.

A likely important feature of the poorly understood aerosol-cloud interactions over the Southern Ocean (SO) is the dominant role of sea spray aerosol, versus terrestrial aerosol. Ice nucleating particles (INPs), or particles required for heterogeneous ice nucleation, present over the SO have not been studied in several decades. In this study, boundary layer aerosol properties and immersion freezing INP number concentrations (nINPs) were measured during a ship campaign that occurred south of Australia (down to 53°S) in March–April 2016. Ocean surface chlorophyll a concentrations ranged from 0.11 to 1.77 mg/m3, and nINPs were a factor of 100 lower than historical surveys, ranging from 0.38 to 4.6 m−3 at −20 °C. The INP population included organic heat-stable material, with contributions from heat-labile material. Lower INP source potentials of SO seawater samples compared to Arctic seawater were consistent with lower ice nucleating site densities in this study compared to north Atlantic air masses.

Acidity is an important chemical variable that impacts atmospheric and snowpack chemistry. Here we describe composite time series and the spatial pattern of acidity concentration (Acy = H+ − HCO3−) during the last 2000 years across the Dronning Maud Land region of the East Antarctic Plateau using measurements in seven ice cores. Coregistered measurements of the major ion species show that sulfuric acid (H2SO4), nitric acid (HNO3), and hydrochloric acid (HCl) determine greater than 98% of the acidity value. The latter, also described as excess chloride (ExCl−), is shown mostly to be derived from postdepositional diffusion of chloride with little net gain or loss from the snowpack. A strong inverse linear relationship between nitrate concentration and inverse accumulation rate provides evidence of spatially homogenous fresh snow concentrations and reemission rates of nitrate from the snowpack across the study area. A decline in acidity during the Little Ice Age (LIA, 1500–1900 Common Era) is observed and is linked to declines in HNO3 and ExCl− during that time. The nitrate decline is found to correlate well with published methane isotope data from Antarctica (δ13CH4), indicating that it is caused by a decline in biomass burning. The decrease in ExCl− concentration during the LIA is well correlated to published sea surface temperature reconstructions in the Atlantic Ocean, which suggests increased sea salt aerosol production associated with greater sea ice extent.

Volcanic signatures in ice-core records provide an excellent means to date the cores and obtain information about accumulation rates. From several ice cores it is thus possible to extract a spatio-temporal accumulation pattern. We show records of electrical conductivity and sulfur from 13 firn cores from the Norwegian-USA scientific traverse during the International Polar Year 2007–2009 (IPY) through East Antarctica. Major volcanic eruptions are identified and used to assess century-scale accumulation changes. The largest changes seem to occur in the most recent decades with accumulation over the period 1963–2007/08 being up to 25% different from the long-term record. There is no clear overall trend, some sites show an increase in accumulation over the period 1963 to present while others show a decrease. Almost all of the sites above 3200 m above sea level (asl) suggest a decrease. These sites also show a significantly lower accumulation value than large-scale assessments both for the period 1963 to present and for the long-term mean at the respective drill sites. The spatial accumulation distribution is influenced mainly by elevation and distance to the ocean (continentality), as expected. Ground-penetrating radar data around the drill sites show a spatial variability within 10–20% over several tens of kilometers, indicating that our drill sites are well representative for the area around them. Our results are important for large-scale assessments of Antarctic mass balance and model validation.

We compare the present and last interglacial periods as recorded in Antarctic water stable isotope records now available at various temporal resolutions from six East Antarctic ice cores: Vostok, Taylor Dome, EPICA Dome C (EDC), EPICA Dronning Maud Land (EDML), Dome Fuji and the recent TALDICE ice core from Talos Dome. We first review the different modern site characteristics in terms of ice flow, meteorological conditions, precipitation intermittency and moisture origin, as depicted by meteorological data, atmospheric reanalyses and Lagrangian moisture source diagnostics. These different factors can indeed alter the relationships between temperature and water stable isotopes. Using five records with sufficient resolution on the EDC3 age scale, common features are quantified through principal component analyses. Consistent with instrumental records and atmospheric model results, the ice core data depict rather coherent and homogenous patterns in East Antarctica during the last two interglacials. Across the East Antarctic plateau, regional differences, with respect to the common East Antarctic signal, appear to have similar patterns during the current and last interglacials. We identify two abrupt shifts in isotopic records during the glacial inception at TALDICE and EDML, likely caused by regional sea ice expansion. These regional differences are discussed in terms of moisture origin and in terms of past changes in local elevation histories, which are compared to ice sheet model results. Our results suggest that elevation changes may contribute significantly to inter-site differences. These elevation changes may be underestimated by current ice sheet models.

The acquisition and interpretation of increasingly high-resolution climate data from polar ice and firn cores motivates the question: What is the finest depth or timescale on which measurements on cores arrayed over a given area correlate? We analyze dated depth series of electrical and oxygen isotope measurements from a spatial array of firn cores with 3.5–7 km spacing in Dronning Maud Land, Antarctica, each with a temporal span of approximately 200 years. We use wavelet analysis to decompose the series into components associated with changes of averages on different scales, and thus deduce which scales are dominated by environmental noise, and which may contain a common signal. We find that common signals in electrical records have timescales of approximately 1–3 years. We identify only one electrical signal which rises significantly above the background in our 200-year records, evidently corresponding to the Tambora eruption. Several smaller signals correlate in a few of pairs of cores, one of which may correspond to a known volcanic event, but the others appear to be spurious. We present a simulation-based method for testing the significance of apparent electrical signal correlations, and highlight the importance of accurate relative dating between cores. In the case of oxygen-isotope records, we find, surprisingly, no significant correlation on any scale in the records, for any of the pairs of cores. There is, however, a weak trend toward positive correlation at longer timescales (up to 16 years). Statistical theory for the relevant confidence intervals and the observed statistics of the records permit estimation of the length of a data series necessary to reliably detect a hypothetical correlation equal to that observed. For the highest correlation observed on 16-year scales, core records of about 380 years (approximately 30 m at the Dronning Maud Land site) would be necessary to establish significance.

An updated compilation of published and new data of major-ion (Ca, Cl, K, Mg, Na, NO3, SO4) and methylsulfonate (MS) concentrations in snow from 520 Antarctic sites is provided by the national ITASE (International Trans-Antarctic Scientific Expedition) programmes of Australia, Brazil, China, Germany, Italy, Japan, Korea, New Zealand, Norway, the United Kingdom, the United States and the national Antarctic programme of Finland. The comparison shows that snow chemistry concentrations vary by up to four orders of magnitude across Antarctica and exhibit distinct geographical patterns. The Antarctic-wide comparison of glaciochemical records provides a unique opportunity to improve our understanding of the fundamental factors that ultimately control the chemistry of snow or ice samples. This paper aims to initiate data compilation and administration in order to provide a framework for facilitation of Antarctic-wide snow chemistry discussions across all ITASE nations and other contributing groups. The data are made available through the ITASE web page (http://www2.umaine.edu/itase/content/syngroups/snowchem.html) and will be updated with new data as they are provided. In addition, recommendations for future research efforts are summarized.

A 100 m long ice core was retrieved from the coastal area of Dronning Maud Land (DML), Antarctica, in the 2000/01 austral summer. The core was dated to AD 1737 by identification of volcanic horizons in dielectrical profiling and electrical conductivity measurement records in combination with seasonal layer counting from high-resolution oxygen isotope (δ18O) data. A mean long-term accumulation rate of 0.29 ma–1w.e. was derived from the high-resolution δ18O record as well as accumulation rates during periods in between the identified volcanic horizons. A statistically significant decrease in accumulation was found from about 1920 to the present. A comparison with other coastal ice cores from DML suggests that this is a regional pattern.

To investigate recent variability in accumulation and δ18O, we synthesize data from five snow cores, covering the period 1932–96, from the sector 16˚38’ W–4˚48’ E in coastal Dronning Maud Land (DML), Antarctica. the δ18O records from the different sites are remarkably similar and suggest a common stable moisture source for this coastal section of DML. While the accumulation pattern is local, and specific features restricted to the individual sites, the overall accumulation pattern is related to the temperature variability as indicated by coastal instrumental records. Accumulation and δ18O correlate between 1955 and 1985 but deviate thereafter, with the proxy-temperature record showing a positive trend while accumulation decreased. This occurs at the same time as an increase in sea-ice extent in the area, which may have resulted in circulation changes and more northerly storm paths. Both stacked accumulation and δ18O records show that large-scale atmospheric signals, as well as some pronounced individual events, are recorded in DML coastal ice cores.

During the 1997/98 field season, Sweden, Norway and The Netherlands performed a pre-site survey for EPICA in Dronning Maud Land, Antarctica. This paper summarizes the results and pays special attention to the high spatial gradients found in snow layering and temperatures. The sites were "Camp Victoria" (CV) on Amundsenisen (76° S, 8° W; 2400 m a.s.l.), approximately 550 km from the coast, and "Camp Maudheimvidda" (CM) on Maudheimvidda (74° S 13° W; 362 m a.s.L), some 140 km from the coast.The drilling programme included both medium-long firn/ice cores and shallow firn cores. These were analysed by means of δ18O, DEP, ECM,β activity, density, and ion content. The combined results suggests a mean annual accumulation rate of 60 mm. we. for CV and 220 mm. we. for CM.Variability measurements of spatial snow layering were performed at two scales; over tens of kilometres by radar and over a few metres by pits and high-resolution radar soundings. Results, as measured by relative standard deviation, were typically 10% on the polar plateau and as high as 50% near the coast.The 10 m temperature measurements were –38.5°C (std dev. = 0.5°) for CV and –17.6°C (std dev.=0.15°) for CM.Snow chemistry was sampled at each medium-long-core drill site. Comparison of δ18O profiles from snow pits and the uppermost part of the CV medium-long core showed large variations. Mean δ18O valuesover 2 m profiles varied between 41.6%, and 39.7%o within a horizontal distance of 50 m.

During the Nordic EPICA pre-site survey in Dronning Maud Land in 1997/1998 a 120 m long ice core was retrieved (76°00′S 08°03′W, 2400 m above sea level). The whole core has been measured using the electric conductivity measurement (ECM) and dielectric profiling (DEP) techniques, and the core chronology has been established by detecting major volcanic eruptions. In a nearby shallow core radioactive traces from nuclear tests conducted during the 1950s and 1960s have been identified. Altogether, 13 ECM and DEP peaks in the long core are identified as originating from specific volcanic eruptions. In addition two peaks of increased total β activity are identified in the short core. Accumulation is calculated as averages over the time periods between these dated events. Accumulation rate is 62 millimetres (w. eq./yr) for the last 181 years (1816 A.D. to present) and 61 mm w. eq./yr for the last 1457 years (540 A.D. to present). Our record shows an 8% decrease in accumulation between 1452 and 1641 A.D. (i.e. part of the Little Ice Age), compared to the long-term mean.

Surface patterns of alternating snow and blue-ice bands are found in the Jutulgryta area of Dronning Maud Land, Antarctica. The snow-accumulation regions exist in the lee of blue-ice topographic ridges aligned perpendicular to winter winds. The snow bands are c. 500–2000 m wide and up to several kilometres long. In Jutulgryta, these features cover c. 5000 km2. These alternating snow and blue-ice bands are simulated using a snow transport and redistribution model, SnowTran-3D, that is driven with a winter cycle of observed daily screen-height air temperature, humidity, and wind speed and direction. The snow-transport model is coupled to a wind model that simulates wind flow over the relatively complex topography. Model results indicate that winter winds interact with the ice topographic features to produce alternating surface patterns of snow accumulation and erosion. In addition, model sensitivity simulations suggest that subtle topographic variations, on the order of 5m elevation change over a horizontal distance of 1 to 1.5 km, can lead to snow-accumulation variations that differ by a factor of six. This result is expected to have important consequences regarding the choice of sites for ice-coring efforts in Antarctica and elsewhere.

As part of the pre-site survey in Dronning Maud Land for the European Project for Ice Goring in Antarctica (EPICA), the spatial variability of snow-layer thickness and snow chemistry was studied at two geographically different ice-core drill sites. The study aimed to quantify error bars on accumulation rates derived from firn and ice cores. One site is located on the polar plateau at Amundsenisen (76° S, 8° W) and the other in the coastal area at Maudheimvidda (73° S, 13° W). Medium-deep ice cores (100 m) and shallow firn cores (10-20 m) were drilled and snow pits (0.5-2 5 m) were dug at each site. At Amundsenisen a large (16 m x 6 m x 2.5 m deep) snow pit was dug. Snow structure in this large snow pit was mapped using optical surveying equipment, and photographically documented. Samples for analysis of nine ions and oxygen isotopes were collected along one depth profile. Density and in situ electrical conductivity measurements were made along three depth profiles! Snow-layer variability was studied in two different areas and at two different scales. At a regional scale, measured by snow-radar soundings, the variability was 8% on the polar plateau and 45% in the coastal area. The variability at a micro-scale in the large snow pit was 9%. The results indicate that ice cores from the polar plateau are more representative for a larger area than ice cores drilled in the coastal area There is no doubt that there are significant error bars on high-resolution accumulation data received from firn and ice cores, especially from the coastal area, but averaging over tens of years reduces the error in accumulation estimates.

During 1996-97 a European Project for Ice Goring in Antarctica (EPIGA) pre-site surveying traverse worked in the area between 70° S, 5° E and 75° S, 15° E in Dronning Maud Land. We present data obtained from 10 and 20 m deep firn cores drilled between the coast and 600 km inland (to 3450 m a.s.l.). The cores were analyzed for electrical conductivity measurements and total β activity to obtain accumulation data between known time horizons. In addition, some of the cores were analyzed for oxygen isotopes. Annual accumulation varies from 271 mm we. at Fimbulisen to 24 mm we at 2840 m a.s.l. Accumulation at core sites 2400-3000 m a.s.l. has increased by 16-48% since 1965 compared to the 1955-65 period. However, the core sites above 3250 m a.s.l. and one core location on the ice shelf show a decrease during the same period. Furthermore, no change can be detected at the most inland site for the period 1815-1996. In all the cores the last few years seem to have been some of the warmest in these records.

We report in this study the distribution of 10Be in the top 40 m of the Renland ice core (East Greenland) and in a 30 m long core from DML (Dronning Maud Land, Antarctica) for the period 1931–1988. The two sites show differences in10Be content, the Antarctica site showing smaller variance and a lower average 10Be annual flux. Similarly, the average accumulation rate (cm water equivalent year−1) is higher in the Renland relative to DML. The variability in accumulation (precipitation) rates seems to explain part of the difference in10Be flux between the two polar sites. Cyclic fluctuations of 10Be flux correlate with the 11-year sunspot number and cosmic ray intensity than with the aa index (perturbation of the geomagnetic activity by the solar wind). Our data corroborate 10Be cyclic fluctuation pattern from the Dye 3 ice core and confirm a promising potential for correlation of global and local events.

During the austral summer 1993/1994, the spatial distribution of snow was mapped by a ground-based snow radar (800–2300 MHz) in western Dronning Maud Land, East Antarctica. Snow radar soundings were performed along continuous profiles extending from the ice shelf up to the polar plateau, a total distance of 1040 km. The high-resolution radar registrations revealed subsurface layering in the uppermost 12 m of the snowpack. The travel time record was translated into snow accumulation expressed in water equivalents, based on an empirical relationship between wave speed and firn density. A good knowledge on snow density variations with depth is essential for the variability studies. Generally, the snow layering was well developed in the coastal area and less well developed on the polar plateau. High spatial variability in snow accumulation was observed on a regional as well as on a local scale. The variability was very high in areas with large surface slopes, such as the grounding zone and around nunataks. The highest variability was recorded in the nunatak area, where the standard deviation reached 59% of the spatial average accumulation. On the smooth high-altitude plateau, variations in accumulation were less pronounced. However, here the standard deviation exceeded 22% of the average accumulation rate. Provided that the snow radar soundings are supported by dating of reference horizons along the travel route, this is a good method to obtain the accumulation rate and pattern for large areas with a high spatial resolution.